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Calcium carbide furnace tail gas waste heat boiler

NegotiableUpdate on 08/18
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Overview

The core equipment for calcium carbide production is the calcium carbide furnace. From the principles and structures of calcium carbide production, calcium carbide furnaces are divided into closed calcium carbide furnaces and open calcium carbide furnaces. In the production of calcium carbide, carbon materials react with lime to produce calcium carbide (calcium carbide) and CO. If the furnace cover of the calcium carbide furnace is fully sealed, a by-product gas is produced, mainly composed of CO. This type of calcium carbide furnace is called a closed type calcium carbide furnace. If the calcium carbide furnace does not have a furnace cover or a dust collection hood is installed above the furnace body for dust removal, the dust collection hood should be as tight as possible, or the opening of the furnace hood should be as small as possible. Due to the by-product CO in the calcium carbide production process coming into contact with the air on the furnace surface, CO2 is quickly formed. This type of calcium carbide furnace is called an open type calcium carbide furnace. China's annual production of calcium carbide ranks first in the world. Since the beginning of the 21st century, the calcium carbide industry in China has been using fully enclosed calcium carbide furnaces, internal combustion enclosed calcium carbide furnaces, and open calcium carbide furnaces. Large scale production bases for commercial calcium carbide are being established in northwest and southwest regions of China, including Inner Mongolia, Ningxia, and Gansu. Such as the 500000 to 1.5 million tons/year calcium carbide base in Ordos, the 1.9 million tons/year calcium carbide base in Xinjiang, and the 1.5 million tons/year calcium carbide base in Qinghai, some of these calcium carbide factories have also introduced the world's most advanced and largest capacity calcium carbide furnaces, ushering in an era of vigorous development of calcium carbide production in China. As is well known, carbide furnace gas has its own latent and sensible heat. For a single 45000 tons/year carbide furnace tail gas waste heat boiler, the furnace gas heat energy is equivalent to saving 7000 tons of standard coal. If we calculate based on China's production capacity of 22 million tons per year for calcium carbide, the country can save 3.3-3.5 million tons of standard coal annually. Therefore, fully .....

Product Details

Working principle

The gas in the calcium carbide furnace is mainly combustible gases such as carbon monoxide, hydrogen, and methane, accounting for about 90%. There are also coke particles in the smoke and dust, so direct combustion can be used to recover heat energy

The direct combustion method of calcium carbide furnace gas is to directly send the calcium carbide furnace gas as fuel into a gas waste heat boiler for combustion, which utilizes both the latent heat and sensible heat of the furnace gas to generate steam and then generate electricity. Due to the combustion of furnace gas in the boiler at a temperature of up to 1500 ℃, its dust is transformed into coarse and heavy non stick particles after calcination, no longer containing tar and cyanide ions. Most of the heat from the furnace gas is absorbed by the water-cooled wall tubes and the circulating tube bundles of the waste heat boiler of the calcium carbide furnace, and is sent to the dust collection equipment after reaching the appropriate exhaust temperature. Conventional cyclones, bag filters, and electrostatic precipitators can all meet the smoke and dust emission standards.

The waste heat utilization device of a calcium carbide furnace can generate electricity by using a boiler to produce steam, or by using an air preheater to produce hot air for other combustion devices in the enterprise to assist combustion, or as a heat source for material drying.

Calcium carbide furnace gas is mainly composed of combustible gases such as carbon monoxide, hydrogen, methane, etc. It is a high-value fuel. Nowadays, calcium carbide furnace enterprises have developed a comprehensive utilization process of waste heat from closed calcium carbide furnaces and white ash kilns. The calcium carbide furnace gas is input into the white ash kiln as a heat source for combustion, releasing its potential. However, due to the production process requirements of the white ash kiln, the input calcium carbide furnace gas must be clean. Therefore, the calcium carbide furnace gas needs to be dedusted using dry or wet methods before being input into the white ash kiln. This makes it a new issue to recover the sensible heat of the furnace gas before purification. Therefore, the non combustion method for recovering the thermal energy of the furnace gas has emerged

As mentioned earlier, the crude furnace gas of the calcium carbide furnace contains volatile substances. When the temperature is below 220 ℃, volatile substances can precipitate oily substances from the furnace gas, causing the oily substances to combine with the dust in the crude furnace gas and accumulate on the equipment, resulting in ash accumulation. Therefore, it is required that the exhaust temperature of the waste heat boiler of the calcium carbide furnace should not be lower than 220 ℃.

For the design of this type of calcium carbide furnace waste heat boiler, it is necessary to solve the difficulties of tar condensation under various working conditions, the difficulties of preventing and cleaning smoke and dust, and the problems of wear and dust accumulation on the pipe wall and timely cleaning of the furnace body caused by smoke and dust. Due to the fact that the gas temperature of the carbide furnace is between 400-600 ℃, reaching 1000 ℃ instantaneously, the heat exchange between the flue gas and the heating surface is mainly convective heat exchange. Therefore, the waste heat boiler of the carbide furnace is composed of convective tube bundles and does not require a radiative heat exchange surface.

Performance characteristics

1. The Zheng Guo internal combustion sealed calcium carbide furnace has a simple process, reliability, and maturity; One time investment saving, low maintenance workload; It has the advantages of small footprint, short construction period, and energy waste.

2. The fully enclosed calcium carbide furnace gas cooling device of Zhengguo has strong adaptability and strong control ability over the temperature of the cooled flue gas. On the one hand, it can separate tar in the collector, and on the other hand, it can prevent the bag from being burned due to high temperature.

3. On the one hand, bag filters can handle high temperature and high concentration flue gas, with high dust removal efficiency, ensuring high-quality gas sources. On the other hand, bag filters have high-strength dust cleaning capabilities, and Zhengguo uses the latest oil repellent and waterproof technology to reduce the infiltration of high-temperature resistant fibers and oils.

4. Install nitrogen seals between all pipeline flanges and use micro positive pressure conveying to prevent furnace gas leakage.

5. The flue gas adopts two-stage cooling measures. Firstly, a water-cooled sleeve is used to reduce the temperature of the flue gas to below 450 ℃. Then, it enters a forced cooler to cool down to 240 ℃ -280 ℃ to avoid tar precipitation. Once the flue gas exceeds the temperature limit, it can be released and nitrogen gas can be added to assist in cooling. Insulation measures should be taken for the conveying pipeline after dust removal to avoid tar precipitation and blockage of the pipeline.

6. Zhengguo integrates research and development, design, equipment operation, management, and control to find the optimal operating conditions and develop the best operating methods for specific user scenarios.

7. The tail gas waste heat boiler of a calcium carbide furnace is a waste heat recovery equipment that recovers the high-temperature, combustible, and ash containing tail gas heat energy generated by the calcium carbide furnace. The furnace is equipped with suitable dust removal equipment, which can significantly reduce the dust emissions from the tail gas of the calcium carbide furnace and alleviate or eliminate environmental pollution.

Type

Calcium carbide furnace tail gas waste heat boiler
Model specifications Rated evaporation capacity (t/h) Rated steam pressure (Mpa) Rated steam temperature (℃) Water supply temperature (℃) Design fuel
Q48.3/650-11.5-1.27-300 11.5 1.27 300 102-104 Waste heat from tail gas of calcium carbide furnace
Q41.8/875-15.5-2.5/400 15.5 2.5 400 104
Process parameters of calcium carbide flue gas from different furnace types
Furnace type Open furnace Semi closed furnace Fully enclosed furnace
Smoke temperature ℃ 160~200 350~550 600~1000
Ton of calcium carbide production, flue gas volume/(m ³/h) 30000 9000 400
Dust concentration (g/m ³) 1~3 38~20 3130~200
oxygen content 19% 17% trace
Carbon monoxide content 1.2% 5% 70%
carbon dioxide content trace trace 5%
Hydrogen content 80.4% 76% 13%
Nitrogen content trace trace More